UC Pd: A New Form of Pd/C for Sonogashira Couplings

Sonogashira cross-couplings of dehydroamino acid derivatives and phenylacetylenes

a new approach to credibility premium for zero-inflated poisson models for panel data

هدف اصلی از این تحقیق به دست آوردن و مقایسه حق بیمه باورمندی در مدل های شمارشی گزارش نشده برای داده های طولی می باشد. در این تحقیق حق بیمه های پبش گویی بر اساس توابع ضرر مربع خطا و نمایی محاسبه شده و با هم مقایسه می شود. تمایل به گرفتن پاداش و جایزه یکی از دلایل مهم برای گزارش ندادن تصادفات می باشد و افراد برای استفاده از تخفیف اغلب از گزارش تصادفات با هزینه پائین خودداری می کنند، در این تحقیق ...

Alkynylation of steroids via Pd-free Sonogashira coupling.

Cu-catalyzed Pd-free Sonogashira coupling has been proposed as a straightforward and convenient route to valuable steroidal enynes. A biligand catalyst system based on Ph3P and TMEDA has been designed. The protocol was utilized for the efficient coupling of iodosteroids with diverse terminal alkynes and 1-trimethylsilylalkynes. A possible role of an auxiliary ligand as a phase-transfer catalyst...

A ligand-free solid-supported system for Sonogashira couplings: applications in nucleoside chemistry.

A mild heterogeneous, ligand-free protocol for Sonogashira and Heck couplings has been developed and used to access several biologically important deoxynucleoside derivatives in a facile manner.

Developing of Ethylene Glycol as a New Reducing Agent for Preparation of Pd-Ag/PSS Composite Membrane for Hydrogen Separation

In the present work, for the first time, a palladium-silver membrane has been prepared by electroless plating on the surface of a porous stainless steel disk by using ethylene glycol as a new reducing agent and polyol process. The reducing action of ethylene-glycol in the presence of PVP as a protecting surface agent produces a membrane with finely divided powder and nano-sized pores. Furthermo...